Issue 1, 2004
From the journal:

Organic & Biomolecular Chemistry

The fluorine-containing π-allylmetal complex. The transition metal-catalyzed allylic substitution reaction of fluorinated allyl mesylates with various carbon nucleophiles

Tsutomu Konno,*a   Tsuyoshi Takehana,a   Takashi Ishiharaa  and  Hiroki Yamanakaa  

* Corresponding authors

a Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan
E-mail: konno@chem.kit.ac.jp
Fax: 81-75-724-7580
Tel: 81-75-724-7573

Abstract

The allylic substitution reaction of α-fluoroalkylated allyl mesylates with various carbon nucleophiles in the presence of transition metal catalyst (Pd and Mo) proceeded with high regioselectivity to give the corresponding γ-fluoroalkylated products in excellent yields.

Graphical abstract: The fluorine-containing π-allylmetal complex. The transition metal-catalyzed allylic substitution reaction of fluorinated allyl mesylates with various carbon nucleophiles

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B310950J
Article type
Paper
Submitted
10 Sep 2003
Accepted
23 Oct 2003
First published
17 Nov 2003

Org. Biomol. Chem., 2004,2, 93-98

Permissions

Request permissions

The fluorine-containing π-allylmetal complex. The transition metal-catalyzed allylic substitution reaction of fluorinated allyl mesylates with various carbon nucleophiles

T. Konno, T. Takehana, T. Ishihara and H. Yamanaka, Org. Biomol. Chem., 2004, 2, 93 DOI: 10.1039/B310950J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements