Issue 16, 2004
From the journal:

Dalton Transactions

Mononuclear nitrogen/sulfur-ligated cobalt(ii) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations†

Kyle J. Tubbs,a   Ewa Szajna,a   Brian Bennett,b   Jason A. Halfen,c   Rex W. Watkins,a   Atta M. Arifd  and  Lisa M. Berreau*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Utah State University, 0300 Old Main Hill, Logan, UT, USA
E-mail: berreau@cc.usu.edu
Fax: +1 435-797-3390
Tel: +1 435-797-1625

b Department of Biophysics, Medical College of Wisconsin, 8701 Watertown Plank Road, Milwaukee, WI, USA
E-mail: bbennett@mcw.edu

c Department of Chemistry, University of Wisconsin-Eau Claire, Eau Claire, WI, USA
E-mail: halfenja@uwec.edu

d Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, Utah, USA
E-mail: arif@chemistry.utah.edu

Abstract

The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic 1H NMR, and cyclic voltammetry.

Graphical abstract: Mononuclear nitrogen/sulfur-ligated cobalt(ii) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

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Article information

DOI
https://doi.org/10.1039/B408177C
Article type
Communication
Submitted
01 Jun 2004
Accepted
09 Jul 2004
First published
20 Jul 2004

Dalton Trans., 2004, 2398-2399

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Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

K. J. Tubbs, E. Szajna, B. Bennett, J. A. Halfen, R. W. Watkins, A. M. Arif and L. M. Berreau, Dalton Trans., 2004, 2398 DOI: 10.1039/B408177C

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