A neutral tungsten-η2-alkyne-1-thio ligand forming a homoleptic Werner type complex with Cu(I)

Wolfram W. Seidel; Maria D. Ibarra Arias; Markus Schaffrath; Klaus Bergander

doi:10.1039/B404821K

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A neutral tungsten-η²-alkyne-1-thio ligand forming a homoleptic Werner type complex with Cu(I)†

Wolfram W. Seidel,*^a Maria D. Ibarra Arias,^a Markus Schaffrath^a and Klaus Bergander^b

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* Corresponding authors

^a Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstraße 36, Münster, Germany
E-mail: seidelww@uni-muenster.de
Fax: (+49) 251 8333108

^b Organisch Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, Münster, Germany

Abstract

The 1-thio-η²-alkyne-complex [Tp′(CO)₂W(BnSCCS)] [Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate; Bn = benzyl], which was obtained by reductive removal of the benzyl group at the alkyne complex [Tp′(CO)₂W(BnSCCSBn)]PF₆, has been established as a ligand in a combined organometallic/Werner type heterobimetallic complex with Cu(I).

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Article information

DOI: https://doi.org/10.1039/B404821K
Article type: Communication
Submitted: 31 Mar 2004
Accepted: 26 May 2004
First published: 04 Jun 2004

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Dalton Trans., 2004, 2053-2054

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A neutral tungsten-η²-alkyne-1-thio ligand forming a homoleptic Werner type complex with Cu(I)

W. W. Seidel, M. D. Ibarra Arias, M. Schaffrath and K. Bergander, Dalton Trans., 2004, 2053 DOI: 10.1039/B404821K

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Dalton Transactions