Issue 101, 2004
From the journal:

CrystEngComm

A novel 2D mixed valence copper(i/ii) rectangular grid constructed with pyrazine and croconate

Tapas Kumar Maji,a   Debajyoti Ghoshal,a   Ennio Zangrando,b   Joan Ribas*c  and  Nirmalendu Ray Chaudhuri*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata- 700 032, India
E-mail: icnrc@iacs.res.in
Fax: +91 33 2473 2805

b Dipartimento di Scienze Chimiche, University of Trieste, 34127 Trieste, Italy

c Departament de Química Inorgánica, Universitat de Barcelona, Diagonal, 6487, 08028 Barcelona, Spain
E-mail: joan.ribas@qi.ub.es

Abstract

A novel 2D rectangular grid coordination polymer with a mixed valence localized copper(I/II), [Cu2ICuII(pyz)2(C5O5)2 (H2O)2]n (pyz, pyrazine; C5O52−, croconate dianion) has been hydrothermally synthesized viain situ redox reaction of Cu(II), and characterized by X-ray diffraction analysis, magnetic and EPR study. The structure extends to a 3D supramolecular network through H-bonding.

Graphical abstract: A novel 2D mixed valence copper(i/ii) rectangular grid constructed with pyrazine and croconate

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Article information

DOI
https://doi.org/10.1039/B414642E
Article type
Communication
Submitted
21 Sep 2004
Accepted
29 Nov 2004
First published
09 Dec 2004

CrystEngComm, 2004,6, 623-626

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A novel 2D mixed valence copper(I/II) rectangular grid constructed with pyrazine and croconate

T. K. Maji, D. Ghoshal, E. Zangrando, J. Ribas and N. R. Chaudhuri, CrystEngComm, 2004, 6, 623 DOI: 10.1039/B414642E

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