Issue 55, 2004
From the journal:

CrystEngComm

Co-chelation of a scorpion-shaped carboxylate ligand and phenanthroline lead to a 2-D interpenetratively tubular architecture†

Xin-Yi Cao,a   Jian Zhang,a   Jian-Kai Cheng,a   Yao Kanga  and  Yuan-Gen Yao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: yyg@fjirsm.ac.cn

Abstract

A novel zinc coordination supramolecular complex, {[Zn3(OABDC)2(phen)3]·2H2O}n, with an open-ended nanotube architecture based on a nano-sized tetranuclear Zn4(OABDC)4 metallacycle repeating unit, is strategically designed and synthesized using a unique scorpion-shaped carboxylate ligand (5-oxyacetate isophthalic acid = H3OABDC) and phenanthroline.

Graphical abstract: Co-chelation of a scorpion-shaped carboxylate ligand and phenanthroline lead to a 2-D interpenetratively tubular architecture

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Article information

DOI
https://doi.org/10.1039/B412700E
Article type
Communication
Submitted
17 Aug 2004
Accepted
20 Sep 2004
First published
27 Sep 2004

CrystEngComm, 2004,6, 315-317

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Co-chelation of a scorpion-shaped carboxylate ligand and phenanthroline lead to a 2-D interpenetratively tubular architecture

X. Cao, J. Zhang, J. Cheng, Y. Kang and Y. Yao, CrystEngComm, 2004, 6, 315 DOI: 10.1039/B412700E

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