Issue 23, 2004
From the journal:

Chemical Communications

Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks†

Atsushi Shimojima*a  and  Kazuyuki Kuroda*ab  

* Corresponding authors

a Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Japan
E-mail: a-shimo@kurenai.waseda.jp; kuroda@waseda.jp
Fax: +81-3-5286-3199
Tel: +81-3-5286-3199

b CREST, Japan Science and Technology Agency (JST), Japan

Abstract

A new class of cage-like oligomers were selectively formed by hydrolysis and polycondensation of a methylene-bridged bistrialkoxysilane precursor in the presence of tetramethylammonium hydroxide, which led to the creation of novel silica-based hybrid materials.

Graphical abstract: Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks

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Article information

DOI
https://doi.org/10.1039/B411794H
Article type
Communication
Submitted
03 Aug 2004
Accepted
24 Aug 2004
First published
14 Oct 2004

Chem. Commun., 2004, 2672-2673

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Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks

A. Shimojima and K. Kuroda, Chem. Commun., 2004, 2672 DOI: 10.1039/B411794H

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