Issue 23, 2004
From the journal:

Chemical Communications

Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle†

José Vicente,*a   María-Teresa Chicote,a   Miguel M. Alvarez-Falcóna  and  Peter G. Jones*b  

* Corresponding authors

a Grupo de Química Organometálica, Departamento de Química Inorgánica, Universidad de Murcia, Aptdo. 4021, Murcia, 30071 Spain
E-mail: jvs1@um.es
Web: http://www.um.es/gqo/
Fax: +34 968 364143
Tel: +34 968 364143

b Institut für Anorganische und Analytische Chemie der Technischen Universität, Postfach 3329, 38023 Braunschweig, Germany
E-mail: p.jones@tu-bs.de

Abstract

trans-[Pt{C[triple bond, length as m-dash]C(Ar)C[triple bond, length as m-dash]CH}2(PMe3)2] (Ar = C6Me4-3,4,5,6) (1) reacts with PPN[Au(acac)2] (Hacac = acetylacetone; 1 ∶ 1.16 molar ratio; PPN = (Ph3P)2N) to give PPN[{Au{Pt(PMe3)2}2}{μ-Ar(C[triple bond, length as m-dash]C)2}3] (2) the crystal structure of which showed the anions as quasi equilateral triangles stacked parallel to each other through C–H⋯Au interactions, resulting in channels of rhombic cross-section.

Graphical abstract: Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B409921D
Article type
Communication
Submitted
01 Jul 2004
Accepted
10 Sep 2004
First published
08 Oct 2004

Chem. Commun., 2004, 2658-2659

Permissions

Request permissions

Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle

J. Vicente, M. Chicote, M. M. Alvarez-Falcón and P. G. Jones, Chem. Commun., 2004, 2658 DOI: 10.1039/B409921D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements