Issue 20, 2004
From the journal:

Chemical Communications

Irreversible or reversible self-assembly procedures yield robust zirconium (iv)-porpyrinphosphonate cones or μm-long fibers of monomolecular thickness

Andreas Klyszcz,a   Matthias Lauer,a   Marta Kopaczynska,a   Christoph Böttcher,a   Ferdinand Gonzagaa  and  Jürgen-Hinrich Fuhrhop*a  

* Corresponding authors

a Freie Universität Berlin, FB Biologie, Chemie, Pharmazie, Institut für Chemie/Organische Chemie, Takustr. 3, D-14195 Berlin, Germany
E-mail: fuhrhop@chemie.fu-berlin.de

Abstract

Stepwise, irreversible self-assembly of porphyrinphosphonates by zirconium(IV) produces cones of 20 nm height and similar widths. Side-on growth cannot be prevented. Reversible fiber growth without metal ions gave micrometer long fibers on mica of 2 nm width, because charge repulsion allowed only for end-on growth.

Graphical abstract: Irreversible or reversible self-assembly procedures yield robust zirconium (iv)-porpyrinphosphonate cones or μm-long fibers of monomolecular thickness

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Article information

DOI
https://doi.org/10.1039/B404267K
Article type
Communication
Submitted
22 Mar 2004
Accepted
27 May 2004
First published
08 Sep 2004

Chem. Commun., 2004, 2358-2359

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Irreversible or reversible self-assembly procedures yield robust zirconium (IV)-porpyrinphosphonate cones or μm-long fibers of monomolecular thickness

A. Klyszcz, M. Lauer, M. Kopaczynska, C. Böttcher, F. Gonzaga and J. Fuhrhop, Chem. Commun., 2004, 2358 DOI: 10.1039/B404267K

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