Issue 16, 2004
From the journal:

Chemical Communications

Highly enantioselective Cu-catalysed asymmetric 1,4-addition of diphenylzinc to cyclohexenone†

Diego Peña,a   Fernando López,a   Syuzanna R. Harutyunyan,a   Adriaan J. Minnaard*a  and  Ben L. Feringa*a  

* Corresponding authors

a Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
E-mail: b.l.feringa@chem.rug.nl
Fax: (+31) 50-3634296
Tel: (+31) 50-3634278

Abstract

Highly enantioselective Cu-catalysed 1,4-addition of diphenylzinc to cyclohexenone has been achieved for the first time using a monodentate phosphoramidite ligand.

Graphical abstract: Highly enantioselective Cu-catalysed asymmetric 1,4-addition of diphenylzinc to cyclohexenone

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Article information

DOI
https://doi.org/10.1039/B402868F
Article type
Communication
Submitted
26 Feb 2004
Accepted
23 Jun 2004
First published
23 Jul 2004

Chem. Commun., 2004, 1836-1837

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Highly enantioselective Cu-catalysed asymmetric 1,4-addition of diphenylzinc to cyclohexenone

D. Peña, F. López, S. R. Harutyunyan, A. J. Minnaard and B. L. Feringa, Chem. Commun., 2004, 1836 DOI: 10.1039/B402868F

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