Jump to main content
Jump to site search

Issue 8, 2004
Previous Article Next Article

Convenient syntheses of “heavy fluorous” cyclopentadienes and cyclopentadienyl complexes with three to five ponytails

Author affiliations

Abstract

Reactions of (η5-C5H5−xBrx)M(CO)3 (M = Re, Mn; x = 1, 3, 4, 5) and IZn(CH2)2Rf8 in the presence of Cl2PdL2 catalysts give the title complexes (η5-C5H5−x((CH2)2Rf8)x)M(CO)3, accompanied in the case of x = 5 by hydride-transfer byproducts. Extremely high fluorophilicities are realized, and the cyclopentadienyl ligands are readily detached () from the manganese complexes.

Graphical abstract: Convenient syntheses of “heavy fluorous” cyclopentadienes and cyclopentadienyl complexes with three to five ponytails

Back to tab navigation

Publication details

The article was received on 02 Feb 2004, accepted on 20 Feb 2004 and first published on 17 Mar 2004


Article type: Communication
DOI: 10.1039/B401540A
Citation: Chem. Commun., 2004,0, 998-999
  •   Request permissions

    Convenient syntheses of “heavy fluorous” cyclopentadienes and cyclopentadienyl complexes with three to five ponytails

    L. V. Dinh and J. A. Gladysz, Chem. Commun., 2004, 0, 998
    DOI: 10.1039/B401540A

Search articles by author

Spotlight

Advertisements