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Issue 9, 2004
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Double asymmetric induction as a mechanistic probe: conjugate addition for the asymmetric synthesis of a pseudotripeptide

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Abstract

Double asymmetric induction as a mechanistic probe indicates that, for the conjugate addition of (R)- and (S)-lithium N-benzyl-N-α-methylbenzylamide to (S)-3′-phenylprop-2′-enoyl-4-benzyloxazolidinone, the reactive conformation of the N-acyl oxazolidinone is the anti-s-cis form, facilitating the asymmetric synthesis of a pseudotripeptide.

Graphical abstract: Double asymmetric induction as a mechanistic probe: conjugate addition for the asymmetric synthesis of a pseudotripeptide

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Publication details

The article was received on 27 Jan 2004, accepted on 10 Mar 2004 and first published on 08 Apr 2004


Article type: Communication
DOI: 10.1039/B401293C
Citation: Chem. Commun., 2004,0, 1128-1129
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    Double asymmetric induction as a mechanistic probe: conjugate addition for the asymmetric synthesis of a pseudotripeptide

    S. G. Davies, G. J. Hermann, M. J. Sweet and A. D. Smith, Chem. Commun., 2004, 0, 1128
    DOI: 10.1039/B401293C

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