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Issue 21, 2003
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Synthesis and crystal structure of a meso-trialkynyl-[28]hexaphyrin

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Abstract

A 5,15,25-trialkynyl [28]hexaphyrin(1.1.1.1.1.1) is the main product of the boron trifluoride-catalysed condensation of meso-anthryl dipyrromethane and triisopropylsilylpropynal; it absorbs strongly in the near-infrared, out to 1093 nm.

Graphical abstract: Synthesis and crystal structure of a meso-trialkynyl-[28]hexaphyrin

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Publication details

The article was received on 12 Jun 2003, accepted on 07 Aug 2003 and first published on 18 Aug 2003


Article type: Communication
DOI: 10.1039/B306725B
Citation: Org. Biomol. Chem., 2003,1, 3639-3641
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    Synthesis and crystal structure of a meso-trialkynyl-[28]hexaphyrin

    A. Krivokapic and H. L. Anderson, Org. Biomol. Chem., 2003, 1, 3639
    DOI: 10.1039/B306725B

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