Issue 11, 2003
From the journal:

Dalton Transactions

Replacement of [RuH2(PMe3)4] by [RuH2(PEt3)4] switches reaction products: synthesis of fluoride-bridged diruthenium complexes

Naseralla A. Jasim,a   Robin N. Perutz*a  and  Stephen J. Archibaldb  

* Corresponding authors

a Department of Chemistry, University of York, York, UK
E-mail: rnp1@york.ac.uk

b Department of Chemistry, University of Hull, Hull, UK

Abstract

The fluoride-bridged ruthenium dimers [Ru2(μ-F)3(PR3)6][F(HF)n] (R = Et, Pr, Bu; n ≈ 3) were synthesised by the reactions of the cis-[RuH2(PR3)4] complexes with NEt3·3HF in THF; the crystal structure of [Ru2(μ-F)3(PEt3)6]OTf, formed by subsequent reaction with NH4OTf, reveals Ru–F distances in the range 2.132(2)–2.170(2) Å and Ru–F–Ru angles in the range 91.72(7)–93.02(7)°.

Graphical abstract: Replacement of [RuH2(PMe3)4] by [RuH2(PEt3)4] switches reaction products: synthesis of fluoride-bridged diruthenium complexes

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Article information

DOI
https://doi.org/10.1039/B301582C
Article type
Paper
Submitted
10 Feb 2003
Accepted
24 Mar 2003
First published
10 Apr 2003

Dalton Trans., 2003, 2184-2187

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Replacement of [RuH2(PMe3)4] by [RuH2(PEt3)4] switches reaction products: synthesis of fluoride-bridged diruthenium complexes

N. A. Jasim, R. N. Perutz and S. J. Archibald, Dalton Trans., 2003, 2184 DOI: 10.1039/B301582C

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