Issue 4, 2003
From the journal:

Dalton Transactions

Stabilising Rh–P coordination by phosphanylalkylcyclopentadienyl ligands

Ann E. C. McConnell,a   Douglas F. Foster,b   Peter Pogorzelec,b   Alexandra M. Z. Slawin,a   David J. Lawc  and  David J. Cole-Hamilton*a  

* Corresponding authors

a School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland
E-mail: djc@st-and.ac.uk

b Catalyst Evaluation and Optimisation Service, School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland

c Hull Research and Technology Centre, BP Chemicals, Salt End, Hull, UK

Abstract

(Phosphanylalkyl/aryl)cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5(2-P,P-dialkyl/arylphosphinoethyl)cyclopentadiene and [RhCl(CO)2]2; the electron donating properties of these ligands have been compared and the P–Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

Graphical abstract: Stabilising Rh–P coordination by phosphanylalkylcyclopentadienyl ligands

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Article information

DOI
https://doi.org/10.1039/B211287F
Article type
Communication
Submitted
15 Nov 2002
Accepted
10 Jan 2003
First published
23 Jan 2003

Dalton Trans., 2003, 510-512

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Stabilising Rh–P coordination by phosphanylalkylcyclopentadienyl ligands

A. E. C. McConnell, D. F. Foster, P. Pogorzelec, A. M. Z. Slawin, D. J. Law and D. J. Cole-Hamilton, Dalton Trans., 2003, 510 DOI: 10.1039/B211287F

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