Issue 88, 2003
From the journal:

CrystEngComm

The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]·11H2O, a novel mixed d–f coordination polymer

Thomas A. Miller,a   John C. Jefferyb  and  Michael D. Ward*ab  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK

b Department of Chemistry, University of Sheffield, Dainton Building, Sheffield, UK
E-mail: m.d.ward@sheffield.ac.uk

Abstract

This communication describes the crystal structure of the mixed-metal coordination polymer {[Sm(H2O)5][Ru(CN)3(bpy)-(μ-CN)-Ru(CN)3(bpy)]·11H2O}∞, which was isolated in low yield from co-crystallisation of K2[Ru(bpy)(CN)4] with Sm(NO3)3·6H2O. This polymeric chain extends along the a-axis and is constructed from cyanide ligands bridging Ru and Sm metal vertices; it contains both hydrophobic and hydrophilic channels, the latter filled with an H-bonded network of water molecules.

Graphical abstract: The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]·11H2O, a novel mixed d–f coordination polymer

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B313122J
Article type
Communication
Submitted
20 Oct 2003
Accepted
26 Nov 2003
First published
04 Dec 2003

CrystEngComm, 2003,5, 495-497

Permissions

Request permissions

The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]·11H2O, a novel mixed d–f coordination polymer

T. A. Miller, J. C. Jeffery and M. D. Ward, CrystEngComm, 2003, 5, 495 DOI: 10.1039/B313122J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements