Issue 16, 2003
From the journal:

Chemical Communications

Green oxidation with aqueous hydrogen peroxide

Ryoji Noyori,*a   Masao Aokib  and  Kazuhiko Satoc  

* Corresponding authors

a Department of Chemistry and Research Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan
E-mail: noyori@chem3.chem.nagoya-u.ac.jp

b Department of Chemistry, Graduate School of Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551, Japan

c Research Institute for Green Technology, National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8565, Japan

Abstract

Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally satisfying manner.

Graphical abstract: Green oxidation with aqueous hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/B303160H
Article type
Feature Article
Submitted
19 Mar 2003
Accepted
11 Jun 2003
First published
30 Jun 2003

Chem. Commun., 2003, 1977-1986

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Green oxidation with aqueous hydrogen peroxide

R. Noyori, M. Aoki and K. Sato, Chem. Commun., 2003, 1977 DOI: 10.1039/B303160H

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