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Issue 12, 2002
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Inclusion compounds with mixed guests: controlled stoichiometries and kinetics of enclathration

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Abstract

The host compound trans-9,10-dihydroxy-9,10-bis(p-tert-butylphenyl)-9,10-dihydroanthracene forms inclusion compounds with DMF, DMSO and acetone of the type H·nG1·(4 − n)G2, with n varying integrally from 0 to 4. The structures of these compounds have been elucidated. The kinetics of enclathration with acetone vapour displays anti-Arrhenius behaviour and the desorption process has a low activation energy of 48.4 kJ mol−1.

Graphical abstract: Inclusion compounds with mixed guests: controlled stoichiometries and kinetics of enclathration

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Publication details

The article was received on 30 Nov 2001, accepted on 03 Oct 2002 and first published on 01 Nov 2002


Article type: Paper
DOI: 10.1039/B110987C
Citation: J. Chem. Soc., Perkin Trans. 2, 2002,0, 1973-1979
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    Inclusion compounds with mixed guests: controlled stoichiometries and kinetics of enclathration

    L. J. Barbour, M. R. Caira, T. le Roex and L. R. Nassimbeni, J. Chem. Soc., Perkin Trans. 2, 2002, 0, 1973
    DOI: 10.1039/B110987C

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