Reaction of [AlH3(OEt2)] (generated in situ from AlCl3 and 3 equivalents of LiAlH4) with one equivalent of PriOH resulted in the formation of the pentanuclear complex [Al5(μ4-O)(μ-OPri)7H6]. Incomplete reaction of AlCl3 and 3 equivalents of LiAlH4, followed by the addition of PriOH, afforded the novel species [Al5(μ5-O)(μ-OPri)8(Cl)H4]. Both complexes have been structurally characterised.
C. J. Carmalt, J. D. Mileham, A. J. P. White and D. J. Williams, New J. Chem., 2002, 26, 902 DOI: 10.1039/B201773N
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