Issue 5, 2002
From the journal:

Mendeleev Communications

First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds

Irena S. Akhrem,*a   Lyudmila V. Afanas'eva,a   Sergei V. Vitta  and  Pavel V. Petrovskiia  

* Corresponding authors

a A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation
E-mail: stan@ineos.ac.ru

Abstract

The carbonylation of C6–C10n-alkanes with CO in the presence of CBr4·2AlBr3 at –40 °C and 1 atm CO leads to the products of non-destructive carbonylation, i.e., the esters of tertiary carboxylic acids, R1C(Me)2COOR and R2(Et)C(Me)COOR, after the workup of reaction mixtures with ROH.

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Article information

DOI
https://doi.org/10.1070/MC2002v012n05ABEH001661
Article type
Paper
Submitted
19 Aug 2002

Mendeleev Commun., 2002,12, 180-182

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First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds

I. S. Akhrem, L. V. Afanas'eva, S. V. Vitt and P. V. Petrovskii, Mendeleev Commun., 2002, 12, 180 DOI: 10.1070/MC2002v012n05ABEH001661

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