Issue 4, 2002

The allylic oxidation of unsaturated steroids by tert-butyl hydroperoxide using surface functionalised silica supported metal catalysts

Abstract

Metal complexes based on Co(II), Cu(II), Mn(II) and V(II) immobilised on mesoporous silica, efficiently catalyse the selective allylic oxidation of unsaturated steroids and valencene, and can be easily recovered and reused.

Graphical abstract: The allylic oxidation of unsaturated steroids by tert-butyl hydroperoxide using surface functionalised silica supported metal catalysts

Article information

Article type
Paper
Submitted
11 Feb 2002
First published
28 Jun 2002

Green Chem., 2002,4, 352-356

The allylic oxidation of unsaturated steroids by tert-butyl hydroperoxide using surface functionalised silica supported metal catalysts

J. A. R. Salvador and J. H. Clark, Green Chem., 2002, 4, 352 DOI: 10.1039/B201500P

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