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Issue 24, 2002
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Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

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Abstract

We report the electrochemical properties of Group 15 quaternary alkyl bistriflimide salts, which have very wide electrochemical windows (between +2.6 and −3.4 V vs. Fc+/Fc for [(Me)4As][N(SO2CF3)2]) when used as supporting electrolytes in MeCN and which can be used for the electrodeposition of very electropositive metals, including Eu, in the molten state.

Graphical abstract: Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

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Publication details

The article was received on 17 Sep 2002, accepted on 08 Nov 2002 and first published on 21 Nov 2002


Article type: Communication
DOI: 10.1039/B208968H
Citation: J. Chem. Soc., Dalton Trans., 2002,0, 4532-4534
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    Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

    A. I. Bhatt, I. May, V. A. Volkovich, M. E. Hetherington, B. Lewin, R. C. Thied and N. Ertok, J. Chem. Soc., Dalton Trans., 2002, 0, 4532
    DOI: 10.1039/B208968H

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