A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O

Vaddypally Shivaiah; Puram V. Narasimha Reddy; Leroy Cronin; Samar K. Das

doi:10.1039/B207149E

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A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H₂O)₇Al(OH)₆Mo₆O₁₈]_n·4nH₂O†

Vaddypally Shivaiah,^a Puram V. Narasimha Reddy,^a Leroy Cronin ‡*^b and Samar K. Das*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, University of Hyderabad, Hyderabad, India
E-mail: skdsc@uohyd.ernet.in

^b Department of Chemistry, University of Glasgow, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk

Abstract

The structure of the complex [La(H₂O)₇Al(OH)₆Mo₆O₁₈]_n·4nH₂O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange “head to tail” in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

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Article information

DOI: https://doi.org/10.1039/B207149E
Article type: Communication
Submitted: 22 Jul 2002
Accepted: 03 Sep 2002
First published: 10 Sep 2002

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J. Chem. Soc., Dalton Trans., 2002, 3781-3782

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A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H₂O)₇Al(OH)₆Mo₆O₁₈]_n·4nH₂O

V. Shivaiah, P. V. Narasimha Reddy, L. Cronin and S. K. Das, J. Chem. Soc., Dalton Trans., 2002, 3781 DOI: 10.1039/B207149E

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Journal of the Chemical Society, Dalton Transactions