Issue 13, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

The effect of Brønsted acids on the stability of oxo-alkoxide and imido-alkoxide complexes of molybdenum

Vernon C. Gibson,*a   Andrew J. Graham,a   Daniel L. Ormsby,a   Brian P. Ward,a   Andrew J. P. Whitea  and  David J. Williamsa  

* Corresponding authors

a Department of Chemistry, Imperial College, South Kensington, London, UK

Abstract

Proton acids are found to catalyse the decomposition of the oxo-alkoxide and imido-alkoxide complexes Mo(O)2(O-t-Bu)2 and Mo(N-2,6-i-Pr2C6H3)2(O-t-Bu)2, respectively; the molecular structure of the tetranuclear molybdenum decomposition product [Mo4(N-2,6-i-Pr2C6H3)6(O-t-Bu)2(μ-O)4(μ3-OH)2] is described.

Graphical abstract: The effect of Brønsted acids on the stability of oxo-alkoxide and imido-alkoxide complexes of molybdenum

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Article information

DOI
https://doi.org/10.1039/B202281H
Article type
Communication
Submitted
06 Mar 2002
Accepted
29 May 2002
First published
11 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2597-2598

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The effect of Brønsted acids on the stability of oxo-alkoxide and imido-alkoxide complexes of molybdenum

V. C. Gibson, A. J. Graham, D. L. Ormsby, B. P. Ward, A. J. P. White and D. J. Williams, J. Chem. Soc., Dalton Trans., 2002, 2597 DOI: 10.1039/B202281H

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