Issue 3, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

A nucleobase–inorganic hybrid polymer consisting of copper bis(phosphopentamolybdate) and cytosine

Jiabao Weng,ab   Maochun Hong,*a   Yucang Liang,a   Qian Shia  and  Rong Caoa  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: hmc@ms.fjirsm.ac.cn

b Department of Chemistry, Fujian Teachers University, Fuzhou, Fujian 350007, P. R. China

Abstract

A nucleobase–inorganic hybrid polymer built from P2Mo5O23 and Cu(II)–cytosine subunits has been prepared; X-ray crystal structure analysis reveals the cytosine molecules weakly coordinate to copper(II) and connect the P2Mo5O23 subunit through hydrogen bonds to form extended 2D networks with complicated hydrogen bonding modes; a bathochromic shift, compared to free cytosine, can be observed in the fluorescence spectra of the hybrid polymer.

Graphical abstract: A nucleobase–inorganic hybrid polymer consisting of copper bis(phosphopentamolybdate) and cytosine

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Article information

DOI
https://doi.org/10.1039/B111457N
Article type
Communication
Submitted
14 Dec 2001
Accepted
17 Dec 2001
First published
10 Jan 2002

J. Chem. Soc., Dalton Trans., 2002, 289-290

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A nucleobase–inorganic hybrid polymer consisting of copper bis(phosphopentamolybdate) and cytosine

J. Weng, M. Hong, Y. Liang, Q. Shi and R. Cao, J. Chem. Soc., Dalton Trans., 2002, 289 DOI: 10.1039/B111457N

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