Issue 90, 2002

Structural diversity within the products of the reaction of Ph2SNH with copper(ii) tetrafluoroborate

Abstract

S,S′-diphenylsulfimide Ph2SNH (1) reacts with copper tetrafluoroborate to give a number of different products including two concomitant polymorphs of [Cu(Ph2SNH)4][BF4]2, the interallogon [Cu(Ph2SNH)4]2[BF4]4 and [Cu(Ph2SNH)4][Cu(Ph2SNH)5][BF4]4, an extremely rare example of a homoleptic system exhibiting four- and five-coordinate metal centres in the same unit cell.

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2002
Accepted
03 Oct 2002
First published
11 Oct 2002

CrystEngComm, 2002,4, 545-547

Structural diversity within the products of the reaction of Ph2SNH with copper(II) tetrafluoroborate

K. E. Holmes, P. F. Kelly and M. R. J. Elsegood, CrystEngComm, 2002, 4, 545 DOI: 10.1039/B209185M

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