Issue 90, 2002
From the journal:

CrystEngComm

Structural diversity within the products of the reaction of Ph2SNH with copper(ii) tetrafluoroborate†

Kathryn E. Holmes,a   Paul F. Kelly*a  and  Mark R. J. Elsegooda  

* Corresponding authors

a Department of Chemistry, Loughborough University, Loughborough, UK
E-mail: P.F.Kelly@lboro.ac.uk

Abstract

S,S′-diphenylsulfimide Ph2SNH (1) reacts with copper tetrafluoroborate to give a number of different products including two concomitant polymorphs of [Cu(Ph2SNH)4][BF4]2, the interallogon [Cu(Ph2SNH)4]2[BF4]4 and [Cu(Ph2SNH)4][Cu(Ph2SNH)5][BF4]4, an extremely rare example of a homoleptic system exhibiting four- and five-coordinate metal centres in the same unit cell.

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Article information

DOI
https://doi.org/10.1039/B209185M
Article type
Communication
Submitted
18 Sep 2002
Accepted
03 Oct 2002
First published
11 Oct 2002

CrystEngComm, 2002,4, 545-547

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Structural diversity within the products of the reaction of Ph2SNH with copper(II) tetrafluoroborate

K. E. Holmes, P. F. Kelly and M. R. J. Elsegood, CrystEngComm, 2002, 4, 545 DOI: 10.1039/B209185M

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