Jump to main content
Jump to site search

Issue 24, 2002
Previous Article Next Article

Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)124-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

Author affiliations

Abstract

The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)124-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.

Graphical abstract: Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

Back to tab navigation

Supplementary files

Publication details

The article was received on 01 Oct 2002, accepted on 17 Oct 2002 and first published on 08 Nov 2002


Article type: Communication
DOI: 10.1039/B209496G
Citation: Chem. Commun., 2002,0, 2980-2981
  •   Request permissions

    Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)124-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

    C. S. Alvarez, A. D. Bond, D. Cave, M. E. G. Mosquera, E. A. Harron, R. A. Layfield, M. McPartlin, J. M. Rawson, P. T. Wood and D. S. Wright, Chem. Commun., 2002, 0, 2980
    DOI: 10.1039/B209496G

Search articles by author

Spotlight

Advertisements