Issue 24, 2002
From the journal:

Chemical Communications

Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)†

Carmen Soria Alvarez,a   Andrew D. Bond,a   Dale Cave,a   Marta E. G. Mosquera,b   Eilís A. Harron,a   Richard A. Layfield,a   Mary McPartlin,c   Jeremy M. Rawson,a   Paul T. Wooda  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

b Departmento de Quimica Organica e Inorganica, Facultad de Quimica, Universidad de Oviedo, Julian Claveria 8, Oviedo, Spain

c School of Chemistry, University of North London, Holloway Road, London, UK

Abstract

The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(μ4-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.

Graphical abstract: Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

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Article information

DOI
https://doi.org/10.1039/B209496G
Article type
Communication
Submitted
01 Oct 2002
Accepted
17 Oct 2002
First published
08 Nov 2002

Chem. Commun., 2002, 2980-2981

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Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

C. S. Alvarez, A. D. Bond, D. Cave, M. E. G. Mosquera, E. A. Harron, R. A. Layfield, M. McPartlin, J. M. Rawson, P. T. Wood and D. S. Wright, Chem. Commun., 2002, 2980 DOI: 10.1039/B209496G

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