Issue 20, 2002
From the journal:

Chemical Communications

Enantioselective total synthesis of (–)-xialenon A

David M. Hodgson,*a   Jean-Marie Galanoa  and  Martin Christlieba  

* Corresponding authors

a Dyson Perrins Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: david.hodgson@chem.ox.ac.uk

Abstract

The first total synthesis of (−)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an α′-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described.

Graphical abstract: Enantioselective total synthesis of (–)-xialenon A

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Article information

DOI
https://doi.org/10.1039/B208485F
Article type
Communication
Submitted
02 Sep 2002
Accepted
16 Sep 2002
First published
24 Sep 2002

Chem. Commun., 2002, 2436-2437

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Enantioselective total synthesis of (–)-xialenon A

D. M. Hodgson, J. Galano and M. Christlieb, Chem. Commun., 2002, 2436 DOI: 10.1039/B208485F

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