Issue 22, 2002
From the journal:

Chemical Communications

Synthesis and crystal structure of 2,3,12,13-tetraalkoxy-21, 23-dithiaporphyrins†

Neeraj Agarwal,a   Sarada P. Mishra,a   Anil Kumar,a   C.-H. Hungb  and  M. Ravikanth*a  

* Corresponding authors

a Indian Institute of Technology, Powai, Mumbai, India
E-mail: ravikanth@chem.iitb.ac.in
Fax: +91-22-5723480
Tel: +91-22-5767176

b Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 50058, Republic of China

Abstract

21,23-Dithiaporphyrins with methoxy, butoxy, octyloxy and dodecyloxy substituents at β-thiophene carbons were synthesised for the first time and the crystal structure of the butoxy derivative indicated that the substituents at the β-thiophene carbons induce more planarity in the porphyrin ring.

Graphical abstract: Synthesis and crystal structure of 2,3,12,13-tetraalkoxy-21, 23-dithiaporphyrins

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Article information

DOI
https://doi.org/10.1039/B208017F
Article type
Communication
Submitted
15 Aug 2002
Accepted
25 Sep 2002
First published
10 Oct 2002

Chem. Commun., 2002, 2642-2643

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Synthesis and crystal structure of 2,3,12,13-tetraalkoxy-21, 23-dithiaporphyrins

N. Agarwal, S. P. Mishra, A. Kumar, C.-H. Hung and M. Ravikanth, Chem. Commun., 2002, 2642 DOI: 10.1039/B208017F

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