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Issue 21, 2002
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A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

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Abstract

The reaction of [Mn12O12(O2CCH2But)16(H2O)4] (1) with a reducing agent followed by recrystallization from CH2Cl2/MeNO2 affords the novel octanuclear complex [Mn8O2(O2CCH2But)14(ButCH2CO2H)4] (2).

Graphical abstract: A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

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Publication details

The article was received on 14 Jul 2002, accepted on 12 Sep 2002 and first published on 27 Sep 2002


Article type: Communication
DOI: 10.1039/B206751J
Citation: Chem. Commun., 2002,0, 2502-2503
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    A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

    C. Boskovic, J. C. Huffman and G. Christou, Chem. Commun., 2002, 0, 2502
    DOI: 10.1039/B206751J

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