Issue 17, 2002

Syntheses and structures of structurally diverse potassium β-diketiminates derived from the ligand [{N(SiMe3)C(Ph)}2CH]

Abstract

The compounds [K{(μ-N(SiMe3)C(Ph))2CH}(thf)2]1, [K{μ-N[upper bond 1 start](SiMe3)C(Ph)C(H)C(Ph)N[upper bond 1 end]H}L]2 [L = (thf)22, tmen 3], [K{μ-NSi[upper bond 1 start](Me)2C(Ph)C(H)C(Ph)N[upper bond 1 end]}(thf)3]24 and [K{N(H)C(Ph)}2CH](thf)0.55 have been prepared from K[{N(SiMe3)C(Ph)}2CH] and the X-ray structures of 14 are reported.

Supplementary files

Article information

Article type
Communication
Accepted
15 Jul 2002
First published
29 Jul 2002

Chem. Commun., 2002, 1920-1921

Syntheses and structures of structurally diverse potassium β-diketiminates derived from the ligand [{N(SiMe3)C(Ph)}2CH]

P. B. Hitchcock, M. F. Lappert, D. Liu and R. Sablong, Chem. Commun., 2002, 1920 DOI: 10.1039/B205296B

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