Issue 13, 2002
From the journal:

Chemical Communications

Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts†

Marc A. Klingshirn,a   Grant A. Broker,a   John D. Holbrey,a   Kevin H. Shaughnessy*a  and  Robin D. Rogers*a  

* Corresponding authors

a The Department of Chemistry and Center for Green Manufacturing, The University of Alabama, Box 870336, Tuscaloosa, AL, USA
E-mail: kshaughn@bama.ua.edu; rdrogers@bama.ua.edu

Abstract

The palladium-catalyzed copolymerization of styrene and CO in an ionic liquid solvent, 1-hexylpyridinium bis(trifluoromethanesulfonyl)imide, gave improved yields and increased molecular weights compared to polymerizations run in methanol.

Graphical abstract: Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts

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Article information

DOI
https://doi.org/10.1039/B203367D
Article type
Communication
Submitted
04 Apr 2002
Accepted
08 May 2002
First published
30 May 2002

Chem. Commun., 2002, 1394-1395

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Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts

M. A. Klingshirn, G. A. Broker, J. D. Holbrey, K. H. Shaughnessy and R. D. Rogers, Chem. Commun., 2002, 1394 DOI: 10.1039/B203367D

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