Issue 5, 2002
From the journal:

Chemical Communications

Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Yu Fu,a   Jian-Hua Xie,a   Ai-Guo Hu,a   Hai Zhou,a   Li-Xin Wanga  and  Qi-Lin Zhou*a  

* Corresponding authors

a State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 94 Weijin Rd., Tianjin 300071, China
E-mail: qlzhou@public.tpt.tj.cn

Abstract

Novel monodentate phosphorus ligands containing the 1,1′-spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).

Graphical abstract: Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

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Article information

DOI
https://doi.org/10.1039/B109827F
Article type
Communication
Submitted
02 Nov 2001
Accepted
22 Jan 2002
First published
07 Feb 2002

Chem. Commun., 2002, 480-481

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Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Y. Fu, J. Xie, A. Hu, H. Zhou, L. Wang and Q. Zhou, Chem. Commun., 2002, 480 DOI: 10.1039/B109827F

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