Issue 10, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Supramolecular complexation of [60]fullerene with hexahomotrioxacalix[3]naphthalenes: a new class of naphthalene-based calixarenes

Shehadeh Mizyed,a   Muhammad Ashram,b   David O. Millera  and  Paris E. Georghiou*a  

* Corresponding authors

a Department of Chemistry, Memorial University of Newfoundland, St. John's, Newfoundland, Canada
E-mail: parisg@mun.ca
Fax: 709-737-3702

b Department of Chemistry, Mu'Tah University, Al Karak, Jordan

Abstract

The hexahomotrioxacalix[3]naphthalenes 4 and 5 which are members of a new class of inherently chiral naphthalene-based calixarenes were evaluated for their supramolecular complexation properties with [60]fullerene (“C60”). The X-ray structure of a (5)2·C60 clathrate was obtained and compared with the supramolecular complexation data obtained by a 1H NMR study of 4 and 5 with C60 in benzene-d6 and toluene-d8.

Graphical abstract: Supramolecular complexation of [60]fullerene with hexahomotrioxacalix[3]naphthalenes: a new class of naphthalene-based calixarenes

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Article information

DOI
https://doi.org/10.1039/B105019M
Article type
Paper
Submitted
06 Jun 2001
Accepted
24 Jul 2001
First published
13 Sep 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 1916-1919

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Supramolecular complexation of [60]fullerene with hexahomotrioxacalix[3]naphthalenes: a new class of naphthalene-based calixarenes

S. Mizyed, M. Ashram, D. O. Miller and P. E. Georghiou, J. Chem. Soc., Perkin Trans. 2, 2001, 1916 DOI: 10.1039/B105019M

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