Jump to main content
Jump to site search

Issue 21, 2001
Previous Article Next Article

Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

Author affiliations

Abstract

Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in satisfactory to reasonable yield via nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (η6-fluorobenzene) chromium tricarbonyl. The enantiomerically pure complex (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.

Graphical abstract: Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

Back to tab navigation

Publication details

The article was received on 09 Aug 2001, accepted on 20 Sep 2001 and first published on 12 Oct 2001


Article type: Paper
DOI: 10.1039/B107237B
Citation: J. Chem. Soc., Perkin Trans. 1, 2001,0, 2850-2855
  •   Request permissions

    Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

    M. R. G. da Costa, M. J. M. Curto, S. G. Davies, J. Sanders and F. C. Teixeira, J. Chem. Soc., Perkin Trans. 1, 2001, 0, 2850
    DOI: 10.1039/B107237B

Search articles by author

Spotlight

Advertisements