Issue 20, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Rapid assembly of anti,anti-1,2,3-triol motifs via stereoselective addition of organometallics to aldehydes obtained from (R′,R′,S,R)-2,3-butane diacetal protected butanetetraol derivatives

Darren J. Dixon,a   Lars Krausea  and  Steven V. Ley*a  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK

Abstract

A predictable stereoselective method for the synthesis of enantiopure anti,anti-1,2,3-triols through the addition of organometallic reagents to the axially disposed aldehyde derived from (R′,R′,S,R)-2,3-butane diacetal protected butanetetraol is described.

Graphical abstract: Rapid assembly of anti,anti-1,2,3-triol motifs via stereoselective addition of organometallics to aldehydes obtained from (R′,R′,S,R)-2,3-butane diacetal protected butanetetraol derivatives

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Article information

DOI
https://doi.org/10.1039/B105118K
Article type
Communication
Submitted
11 Jun 2001
Accepted
13 Sep 2001
First published
01 Oct 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2516-2518

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Rapid assembly of anti,anti-1,2,3-triol motifs via stereoselective addition of organometallics to aldehydes obtained from (R′,R′,S,R)-2,3-butane diacetal protected butanetetraol derivatives

D. J. Dixon, L. Krause and S. V. Ley, J. Chem. Soc., Perkin Trans. 1, 2001, 2516 DOI: 10.1039/B105118K

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