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Issue 12, 2001
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Palladium catalysed elaboration of codeine and morphine

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Abstract

Palladium catalysed coupling reactions of 6-O-tert-butyldimethylsilyl-1-bromocodeine and 6-O-tert-butyldimethylsilyl-3-trifluoromethylsulfonylmorphine allow a range of substituted analogues of codeine in the 1-position and morphine in the 3-position to be efficiently and selectively prepared.

Graphical abstract: Palladium catalysed elaboration of codeine and morphine

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Publication details

The article was received on 20 Mar 2001, accepted on 03 May 2001 and first published on 22 May 2001


Article type: Paper
DOI: 10.1039/B102581N
Citation: J. Chem. Soc., Perkin Trans. 1, 2001,0, 1413-1420
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    Palladium catalysed elaboration of codeine and morphine

    S. G. Davies, C. J. Goodwin, D. Pyatt and A. D. Smith, J. Chem. Soc., Perkin Trans. 1, 2001, 0, 1413
    DOI: 10.1039/B102581N

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