Issue 11, 2001
From the journal:

New Journal of Chemistry

Anion exchange properties of a two-dimensional coordination framework of cadmium(II) with 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene†

Bin Sui,a   Jian Fan,a   Taka-aki Okamura,b   Wei-Yin Sun*a  and  Norikazu Ueyamab  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing Uniersity, Nanjing, China
E-mail: sunwy@netra.nju.edu.cn

b Department of Macromolecular Science, Graduate School of Science, Osaka Uniersity, Toyonaka, Osaka, Japan

Abstract

A novel 2D coordination polymer, {[Cd(dimb)2(MeOH)2](ClO4)2}n where dimb = 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene, was synthesized by treatment of Cd(ClO4)2·6H2O with the dimb ligand in methanol solution. The complex was characterized by X-ray crystallography; the coordination geometry around Cd(II) is a slightly distorted octahedron with an N4O2 donor set. The results of IR and elemental analysis show that the perchlorate anion can be partially exchanged by the tetrafluoroborate anion and indicate that the framework has anion exchange properties.

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Article information

DOI
https://doi.org/10.1039/B106750H
Article type
Letter
Submitted
24 Jul 2001
Accepted
13 Aug 2001
First published
12 Oct 2001

New J. Chem., 2001,25, 1379-1381

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Anion exchange properties of a two-dimensional coordination framework of cadmium(II) with 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene

B. Sui, J. Fan, T. Okamura, W. Sun and N. Ueyama, New J. Chem., 2001, 25, 1379 DOI: 10.1039/B106750H

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