Issue 6, 2001
From the journal:

New Journal of Chemistry

Dehalogenation of polychloroarenes with sodium formate in propan-2-ol catalyzed by RhCl(PPh3)3

María A. Atienza,a   Miguel A. Esteruelas,*b   Marta Fernández,a   Juana Herreroa  and  Montserrat Olivánb  

* Corresponding authors

a Departamento de Química, Uniersidad de Cantabria, Santander, Spain

b Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Uniersidad de Zaragoza-C.S.I.C., Zaragoza, Spain
E-mail: maester@posta.unizar.es

Abstract

Polychloroarenes can be dehalogenated with sodium formate in propan-2-ol using RhCl(PPh3)3 as the catalyst. The hydrogenolysis of 1,2,4-trichlorobenzene is selective to 1,2-dichlorobenzene, whereas the hydrogenolysis of 1,3- and 1,4-dichlorobenzene is sequential and selective according to the sequence: chlorobenzene > benzene.

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Article information

DOI
https://doi.org/10.1039/B102191P
Article type
Letter
Submitted
05 Mar 2001
Accepted
20 Apr 2001
First published
16 May 2001

New J. Chem., 2001,25, 775-776

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Dehalogenation of polychloroarenes with sodium formate in propan-2-ol catalyzed by RhCl(PPh3)3

M. A. Atienza, M. A. Esteruelas, M. Fernández, J. Herrero and M. Oliván, New J. Chem., 2001, 25, 775 DOI: 10.1039/B102191P

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