Issue 7, 2001
From the journal:

New Journal of Chemistry

Solid-state self-assembly of a complex from 1,3,5-benzenetricarboxylic acid and 1,3,5-trihydroxybenzene: influence of strong O–H···O and C–H···O hydrogen bonds

Rong Liu,a   Kum-Fun Moka  and  Suresh Valiyaveettil*a  

* Corresponding authors

a Department of Chemistry, National Uniersity of Singapore, 3 Science Drie 3, Singapore
E-mail: chmsv@nus.edu.sg

Abstract

1,3,5-Benzenetricarboxylic acid (trimesic acid, TMA) was cocrystallized with 0.5 equiv. of 1,3,5-trihydroxybenzene (phloroglucinol, THB) to generate a close-packed non-interpenetrating planar mosaic motif. Both O–H···O and C–H···O hydrogen bonds were observed in the crystal lattice. Each THB molecule is hydrogen bonded to six adjacent TMA molecules to form a planar rosette-shaped structure, which constitutes the repeating units of a layer-type lattice.

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Article information

DOI
https://doi.org/10.1039/B102098F
Article type
Letter
Submitted
05 Mar 2001
Accepted
22 May 2001
First published
14 Jun 2001

New J. Chem., 2001,25, 890-892

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Solid-state self-assembly of a complex from 1,3,5-benzenetricarboxylic acid and 1,3,5-trihydroxybenzene: influence of strong O–H···O and C–H···O hydrogen bonds

R. Liu, K. Mok and S. Valiyaveettil, New J. Chem., 2001, 25, 890 DOI: 10.1039/B102098F

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