Metal–metal interactions across bridging elemental carbon chains: a computational study of odd-carbon complexes†
Abstract
Structure,
bonding and metal–metal interactions in complexes [LyMCxM′Ly′′]z+ with odd-carbon chains, and monometallic reference compounds, are investigated at the B3LYP density functional level of theory. The data show strong
rhenium–manganese interactions in [(η5-C5H5)(NO)(PH3)ReCxMn(CO)2(η5-C5H5)]+ (x
= 3, 5, 7, 9), as evidenced by bond lengths
and orders, charge distributions, and negative homodesmotic energies (which diminish with chain length).
Natural bond orbital (NBO) analyses give ground states with highly polarized Re–C bonds, and suggest dominant +Re–(CC)n
C
Mn as opposed
to +Re
(C
C)n
C
Mn character. The corresponding dirhenium complexes are similar but with dominant Re(–C
C)n–C
Re+ character.
The more symmetrical uncharged complexes (η5-C5H5)(CO)2M(1)CxM(2)(CO)2(η5-C5H5) [x
= 3, 5; M(1), M(2) = Re
or Mn] exhibit analogous geometric, electronic and homodesmotic energy trends, but have dominant M
(C
C)n
C
M character. In contrast,
(η5-C5H5)(NO)(PH3)ReC3W(OMe)3 which has a ReC
CC
W linkage, shows no significant (net) rhenium–tungsten interactions.
All geometric and electronic properties are very close to those of monometallic reference compounds. Homodesmotic
energies are near zero, although related triple bond metatheses used preparatively are exothermic.
The dimerization of (MeO)3W
CH is exothermic (−14.6 kcal mol−1), giving a methoxy-bridged structure closely
resembling literature compounds.