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Issue 6, 2001
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Solvent-free synthesis of calix[4]resorcinarenes

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Abstract

Calix[4]resorcinarenes may be prepared in high yield and purity by direct reaction of resorcinol and benzaldehyde derivatives in the presence of a catalytic amount of solid acid and at ambient temperature under solvent-free conditions. This represents a viable alternative to traditional solution phase methodology. The solvent-free method measures up well with respect to energy usage, solvent wastes and associated hazards, reaction time and yield. In addition, the relevant benzaldehyde derivatives are prepared in polypropylene glycol, which is readily recycled.

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Publication details

The article was received on 21 May 2001 and first published on 09 Oct 2001


Article type: Paper
DOI: 10.1039/B104430N
Citation: Green Chem., 2001,3, 280-284
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    Solvent-free synthesis of calix[4]resorcinarenes

    B. A. Roberts, G. W. V. Cave, C. L. Raston and J. L. Scott, Green Chem., 2001, 3, 280
    DOI: 10.1039/B104430N

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