Issue 5, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

[CN3H6]2[Zn(CO3)2], the first organically templated open-framework carbonate

William T. A. Harrison,*a   Mark L. F. Phillips,b   Tina M. Nenoff,c   Elizabeth J. MacLean,d   Simon J. Teatd  and  Robert S. Maxwelle  

* Corresponding authors

a Department of Chemistry, University of Aberdeen, Aberdeen, UK
E-mail: w.harrison@abdn.ac.uk

b 27468 Hayward Boulevard, Hayward, USA

c Sandia National Laboratories, Environmental Monitoring and Characterization, MS 0755, PO Box 5800, Albuquerque, USA

d CCLRC Daresbury Laboratory, Warrington, UK

e Lawrence Livermore National Laboratory, L-226, PO Box 808, Livermore, USA

Abstract

[CN3H6]2[Zn(CO3)2], the first organically templated open-framework carbonate has been synthesized hydrothermally and its single crystal structure and some properties have been determined. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and CO3 building units encapsulating the extra-framework guanidinium cations. Template-to-framework hydrogen bonding appears to play an important role in stabilizing the structure. The zincocarbonate framework shows a surprising similarity to those of known zinc phosphates and phosphites.

Graphical abstract: [CN3H6]2[Zn(CO3)2], the first organically templated open-framework carbonate

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Article information

DOI
https://doi.org/10.1039/B009641P
Article type
Paper
Submitted
01 Dec 2000
Accepted
23 Jan 2001
First published
15 Feb 2001

J. Chem. Soc., Dalton Trans., 2001, 546-549

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[CN3H6]2[Zn(CO3)2], the first organically templated open-framework carbonate

W. T. A. Harrison, M. L. F. Phillips, T. M. Nenoff, E. J. MacLean, S. J. Teat and R. S. Maxwell, J. Chem. Soc., Dalton Trans., 2001, 546 DOI: 10.1039/B009641P

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