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Issue 23, 2001
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A surprisingly mild and versatile method for palladium-catalyzed Suzuki cross-couplings of aryl chlorides in the presence of a triarylphosphine

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Abstract

In the presence of new air-stable triarylphosphine 2, palladium-catalyzed Suzuki reactions of a wide array of aryl chlorides can be accomplished in uniformly good yield, including couplings of very sterically demanding and electronically deactivated substrates; activated aryl chlorides can be coupled at room temperature. In terms of scope and mildness, Pd–2 compares well with other catalyst systems that have been described for Suzuki reactions of aryl chlorides, thereby establishing that triarylphosphines should be regarded as fertile ground for future ligand-design efforts for palladium-catalyzed couplings of aryl chlorides.

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Publication details

The article was received on 30 Aug 2001, accepted on 21 Sep 2001 and first published on 08 Nov 2001


Article type: Communication
DOI: 10.1039/B107888G
Citation: Chem. Commun., 2001, 2408-2409
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    A surprisingly mild and versatile method for palladium-catalyzed Suzuki cross-couplings of aryl chlorides in the presence of a triarylphosphine

    S. Liu, M. J. Choi and G. C. Fu, Chem. Commun., 2001, 2408
    DOI: 10.1039/B107888G

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