Issue 22, 2001

Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

Abstract

Chiral ruthenium(II) complexes, RuCl2(PPh3)(oxazolinylferrocenylphosphine), have been found to be effective catalysts for asymmetric hydrosilylation of ketoximes to give the corresponding primary amines in good yields with high enantioselectivities (up to 89% ee) after acid hydrolysis.

Graphical abstract: Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

Article information

Article type
Communication
Submitted
19 Jul 2001
Accepted
10 Oct 2001
First published
26 Oct 2001

Chem. Commun., 2001, 2360-2361

Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura and M. Hidai, Chem. Commun., 2001, 2360 DOI: 10.1039/B106435P

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