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Issue 19, 2001
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The first observation of the [Cp3Mn] anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thf

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Abstract

Hexagonal [(η2-Cp)3MnK·1.5thf] 1 and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn] anion.

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Publication details

The article was received on 17 Jul 2001, accepted on 21 Aug 2001 and first published on 28 Sep 2001


Article type: Communication
DOI: 10.1039/B106366A
Citation: Chem. Commun., 2001, 1956-1957
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    The first observation of the [Cp3Mn] anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thf

    A. D. Bond, R. A. Layfield, J. A. MacAllister, M. McPartlin, J. M. Rawson and D. S. Wright, Chem. Commun., 2001, 1956
    DOI: 10.1039/B106366A

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