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Issue 18, 2001
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Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2{S2C2(CN)2}2] in the model reductive half reaction of sulfite oxidase

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Abstract

pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.

Graphical abstract: Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2{S2C2(CN)2}2] in the model reductive half reaction of sulfite oxidase

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Publication details

The article was received on 18 Jun 2001, accepted on 02 Aug 2001 and first published on 22 Aug 2001


Article type: Communication
DOI: 10.1039/B105341H
Citation: Chem. Commun., 2001,0, 1786-1787
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    Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2{S2C2(CN)2}2] in the model reductive half reaction of sulfite oxidase

    K. Nagarajan, P. K. Chaudhury, B. R. Srinivasan and S. Sarkar, Chem. Commun., 2001, 0, 1786
    DOI: 10.1039/B105341H

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