Issue 15, 2001
From the journal:

Chemical Communications

Diastereomeric separation of [{M(Cp*)(ado)}3]3+ (M = RhIII, IrIII; ado = adenosinato): crystal structure of an inclusion compound [{Rh(Cp*)(ado)}3](CF3SO3)3 ·MeOH

Kazuaki Yamanari,*a   Rie Ito,a   Shiori Yamamotoa  and  Akira Fuyuhiroa  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, 1-16 Machikaneyama-cho, Toyonaka, Osaka, Japan.
E-mail: yamanari@ch.wani.osaka-u.ac.jp

Abstract

A diastereomer with a C3 cyclic trimer [{Rh(adenosine)(Cp*)}3](CF3SO3) 3, which was obtained selectively by a second-order asymmetric transformation, can include one methanol molecule into its triangle dome-like cavity.

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Article information

DOI
https://doi.org/10.1039/B102870G
Article type
Communication
Submitted
28 Mar 2001
Accepted
21 Jun 2001
First published
12 Jul 2001

Chem. Commun., 2001, 1414-1415

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Diastereomeric separation of [{M(Cp*)(ado)}3]3+ (M = RhIII, IrIII; ado = adenosinato): crystal structure of an inclusion compound [{Rh(Cp*)(ado)}3](CF3SO3)3 ·MeOH

K. Yamanari, R. Ito, S. Yamamoto and A. Fuyuhiro, Chem. Commun., 2001, 1414 DOI: 10.1039/B102870G

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