Issue 15, 2001
From the journal:

Chemical Communications

Nitration of alkanes with nitric acid catalyzed by N-hydroxyphthalimide

Shinji Isozaki,a   Yoshiki Nishiwaki,a   Satoshi Sakaguchia  and  Yasutaka Ishii*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering and High Technology Research Center, Kansai University, Suita, Osaka, Japan.
E-mail: ishii@ipcku.kansai-u.ac.jp

Abstract

Catalytic nitration of alkanes with nitric acid was first successfully achieved by the use of N-hydroxyphthalimide (NHPI) under mild conditions; the key to the present nitration was found to be the in situ generation of NO2 and phthalimide N-oxyl radical by the reaction of NHPI with nitric acid.

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Article information

DOI
https://doi.org/10.1039/B102374H
Article type
Communication
Submitted
13 Mar 2001
Accepted
11 Jun 2001
First published
05 Jul 2001

Chem. Commun., 2001, 1352-1353

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Nitration of alkanes with nitric acid catalyzed by N-hydroxyphthalimide

S. Isozaki, Y. Nishiwaki, S. Sakaguchi and Y. Ishii, Chem. Commun., 2001, 1352 DOI: 10.1039/B102374H

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