Issue 7, 2001

Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet–Taft solvent parameters

Abstract

The Kamlet–Taft solvent parameters π*, α, and β of saturated liquid water have been determined from 25 to 275 °C based on solvatochromic measurements and indicate that the polarity and hydrogen-bonding of water are highly tunable properties with temperature.

Article information

Article type
Communication
Submitted
09 Jan 2001
Accepted
20 Feb 2001
First published
16 Mar 2001

Chem. Commun., 2001, 665-666

Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet–Taft solvent parameters

J. Lu, J. S. Brown, C. L. Liotta and C. A. Eckert, Chem. Commun., 2001, 665 DOI: 10.1039/B100425P

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