Autocatalytic ring opening of N-acylaziridines. Complete control over regioselectivity by orientation at interfaces

Peter J. J. A. Buijnsters; Martinus C. Feiters; Roeland J. M. Nolte; Nico A. J. M. Sommerdijk; Binne Zwanenburg

doi:10.1039/B009294K

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Autocatalytic ring opening of N-acylaziridines. Complete control over regioselectivity by orientation at interfaces

Peter J. J. A. Buijnsters, Martinus C. Feiters, Roeland J. M. Nolte, Nico A. J. M. Sommerdijk and Binne Zwanenburg

Chem. Commun., 2001, 269-270

DOI: 10.1039/B009294K
Received 20 Nov 2000, Accepted 20 Dec 2000
First published online 23 Jan 2001

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Ring opening of 1-alkanoyl-2-phenoxymethylaziridines by phosphate ions yielding self-assembling phospholipid analogues proceeds in an autocatalytic fashion and with complete regioselectivity at an organic–aqueous interface.

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Peter J. J. A. Buijnsters
Martinus C. Feiters
Roeland J. M. Nolte
Nico A. J. M. Sommerdijk
Binne Zwanenburg

Chemical Communications

Autocatalytic ring opening of N-acylaziridines. Complete control over regioselectivity by orientation at interfaces

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